Terpyridine based self-assembly
Web8 Feb 2024 · Coordination-driven self-assembly has emerged as a powerful bottom-up approach to construct various supramolecular architectures with increasing complexity and functionality. Tetraphenylethylene ... Web11 Jun 2016 · A novel, tetrakisterpyridinyl-substituted porphyrin underwent self-assembly to form a three-dimensional, belt-shaped metallomacrocycle, which was characterized by 1D and 2D NMR and electrospray ionization traveling wave ion mobility mass spectrometry. ... Self-Assembly of a Polycyclic, Terpyridine-Based Nanobelt. J Inorg Organomet Polym …
Terpyridine based self-assembly
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Web3 Mar 2024 · In order to realize sustainable polymeric photoactive systems, we developed terpyridine (tpy)-based polymers and their ruthenium complexes, which were reversibly … Web9 Jun 2024 · We developed a simple method to prepare one gold-based metallotweezer with two planar Au-pyrene-NHC arms bound by a 2,6-bis(3-ethynyl-5-tert-butylphenyl)pyridine unit. This metallotweezer is able to bind a series of polycyclic aromatic hydrocarbons through the π-stacking interactions between the polyaromatic guests and the pyrene moieties of …
WebThe terpyridine ligands were synthesized in high yields via a key Suzuki coupling. Restrictions of the possible outcomes for self-assembly ultimately provided optimum … Web1 Aug 2024 · Here we describe the self-assembly of 3-D giant metallo-supramolecular cubes using three-armed terpyridine ligands constructed on adamantane with molecular weight up to 18 k and edge length at $4. ...
WebA fluorescent supramolecular polymer network with an excellent triple-stimuli responsive property based on metal-ligand coordination and host-guest interactions has been constructed from a terpyridine-monofunctionalized leaning tower[6]arene, a tetraphenylethylene AIEgen, and a bridging coordination ion(Zn2+).Addition of competitive … WebHerein, we present a type of well-ordered nanoribbon, which was self-assembled via shape complimentary and hydrophobic effects from the bowl-shaped supramolecular components, which were synthesized by combining designer terpyridine-based monomers and two different metal ions (Ru 2+, Zn 2+ ).
Web1 Aug 2024 · Accordingly, we report the self-assembly of two 2,2′:6″,2″-terpyridine (tpy)-based metallacages with tunable luminescence properties. The final discrete M 6 L 3 cages were formed by the coordination between TPE-based tpy ligands and Zn(II). The structures of the supramolecules were characterized fully by NMR and mass spectrometry, and the ...
Web28 Jun 2024 · A carboxylic acid-containing terpyridine-based hydrogelator (TPPCA) is synthesized to afford a self-assembly induced TPPCA hydrogel, which was used as an all-in-one electrochrome in electrochromic devices (ECDs) to demonstrate reversible transparent-to-black electrochromism with fast darkening and bleaching time of 8.3 s and 9.5 s, … brenda garrett cookbookWeb15 Feb 2024 · The aqueous Zn-air battery also shows appreciable stability with a low voltage window and adequate specific capacity. The observations inspire and suggest that TPA-based π-conjugated metal-organic coordination polymers pave the way for the development of a new and efficient tri-functional electrocatalyst. countdown goldWebThe present highlight review describes the recent synthetic advances in construction of tpy-based self-assembled heteroleptic coordination complexes. Apparently, the rational … brenda gaufo daly city